Syntheses of 2,9-Bis(halomethyl)-1,10-phenanthroline: Potential Robust Ligands for Metal Oxidation Catalysts
Abstract
Free radical halogenation of 2,9-dimethyl-1,10-phenanthroline with N- bromosuccinimide and N-chlorosuccinimide form the known alpha methyl derivatives 2,9-bis(trihalomethyl)-1,10-phenanthroline can be used for one-step syntheses of oxidatively resistant fluoro- and partially reduced chloromethyl derivatives capable of coordination to metal oxidation catalysts. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1993
- Accession Number
- ADA266710
Entities
People
- José Luis González
- Robert H. Beer
- Russell S. Drago
Organizations
- University of Florida