Assessment of Chromate and Non-Chromate Conversion Coatings for Al Alloys Using Electrochemical Impedance Spectroscopy

Abstract

A study was conducted to evaluate whether a non-chromate conversion coating (Sanchem) for Al alloys (Al 2024 and 7075) could be a suitable replacement for the currently used chromate conversion coating (Alodine) without compromising corrosion resistance. Electrochemical impedance spectroscopy (EIS) and salt spray testing were employed to compare the corrosion behavior of coatings consisting of (a) pretreatment only (Sanchem or Alodine), (b) pretreatment (Sanchem or Alodine) plus primer (epoxy polyamide or waterborne epoxy), and (c) pretreatment (Sanchem or Alodine) plus epoxy polyamide primer plus polyurethane topcoat. Results indicated that the experimental impedance values provided a reliable estimate of the film integrity and corrosion protective capability, that the Sanchem conversion coating generally compared favorably with the Alodine coating, and that higher impedance values attributed to the application of topcoat of both alloys which were treated with either Sanchem or Alodine and epoxy polyamide are characteristic of low conductivity, good barrier type coatings. However, additional tests are required before the Sanchem can be recommended as a reliable alternative to the Alodine coating.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1993
Accession Number
ADA267205

Entities

People

  • Fang-Kai Chang
  • M. Levy
  • R. Huie

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Aerial Warfare
  • Air Force
  • Alloys
  • Biomedical And Dental Materials
  • Chromium Compounds
  • Coatings
  • Corrosion Resistance
  • Engineering
  • Films
  • Information Processing
  • Materials
  • Materials Science
  • Measurement
  • Military Research
  • Plastics
  • Standards
  • Warfare

Fields of Study

  • Materials science

Readers

  • Surface Coatings Technology.