The Crystallization of Acetylcholinesterase (AChE) from Torpedo Electric Organ

Abstract

The objective of this project is the crystallization of the enzyme acetylcholinesterase (AChE), with the long-term objective of determining its three-dimensional structure and, thereby, the detailed topography of its active site. Torpedo electric organ was selected since it is a rich source of AChE and possesses an amino acid sequence very similar to that of mammalian AChE. A dimeric form of this enzyme was purified by a procedure which involved selective solubilization with a phosphatidylinositol-specific phospholipase C of bacterial origin, followed by affinity chromatography employing a Sepharose conjugate of a suitable quaternary affinity ligand. A highly purified AChE preparation was obtained in amounts which permitted a systematic attempt to crystallize the enzyme. In order to obtain a crystal form of the ACHE preparation suitable for high-resolution X-ray studies, we examined hundreds of different crystallization conditions. As a result we were able to obtain three (3) different crystal forms which diffract to better than 3 A resolution.... RAV, Acetylcholinesterase, X- Ray Crystallography, Torpedo californica, Crystallization, Three-dimensional structure, Enzymes, Acetylcholine.

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Document Details

Document Type
Technical Report
Publication Date
Jul 18, 1991
Accession Number
ADA268487

Entities

People

  • I. Silman
  • J. L. Sussman

Organizations

  • Weizmann Institute of Science

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Alcohols
  • Amino Acids
  • Animal Structures
  • Chemistry
  • Chromatography
  • Crystallization
  • Crystals
  • Diffraction
  • Enzymes
  • Fish
  • High Resolution
  • Liquid Chromatography
  • Macromolecules
  • Security
  • Three Dimensional
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

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