Dense Energetic Compounds of C, H, N, and O Atoms. III. 5-(4-Nitro-(1,2, 5)oxadiazolyl)-5H-(1,2,3)triazolo(4,5-c)(1,2,5)oxadiazole

Abstract

Diazidoazofurazan 8 was obtained from the bis-diazonium salt of diaminoazofurazan 7 by treatment with sodium azide and underwent thermolysis to 5-(4-azido-(1,2,5)oxadiazolyl)-5H-(1,2,3)triazolo(4,5,-c)(1,2,5)oxadiazole 5. The corresponding amine 13 was obtained from the azide 5 by reduction with stannous chloride and was oxidized by ammonium persulfate to 5-(4 nitro-(1,2,5) oxadiazolyl)-5H-(1,2,3)triazolo(4,5-c)(1,2,5)oxadiazole 1. The azide 5 was converted to a phosphinimine 9 in a reaction with triphenylphosphine

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Document Details

Document Type
Technical Report
Publication Date
Jul 21, 1993
Accession Number
ADA268715

Entities

People

  • Ananthakrishnan Gunasekaran
  • Joseph H. Boyer

Organizations

  • University of New Orleans

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alcohols
  • Alkanes
  • Chemical Synthesis
  • Chemistry
  • Dielectric Gases
  • Energetic Materials
  • Hydrogen
  • Materials
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • New York
  • Organic Chemistry
  • Sodium
  • Sodium Azides
  • Sodium Compounds
  • United States

Fields of Study

  • Chemistry

Readers

  • Allergy and Immunology.
  • Organic Chemistry