Synthesis and Antimuscarinic Activity of 2-(N-(Ethyl)-(N-Beta- Hydroxyethyl)) Aminoethyl 2,2-Diphenylpropionate, a Metabolite of Aprophen

Abstract

The preparation of 2-(N-(ethyl)-(N-beta-hydroxyethyl)aminoethyl 2,2- diphenylpropionate (1), a metabolite of aprophen 12-diethylaminoethyl 2,2- diphenylpropionate) is described. Hydrolysis of 2-(2-chloroethyl) ethylaminolethyl acetate hydrochloride (2) In a basic solution, followed by acidic pH adjustment, gave the ethylcholineaziridinium ion (3) that upon treatment with 2,2-diphenylpropionic acid produced 1 in a 56% yield. Synthetic 1 was found to possess antimuscarinic activities, but was approx. 10-fold less potent than the parent compound aprophen.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1993
Accession Number
ADA269081

Entities

People

  • Haim Leader
  • Lawrence R. Phillips
  • Nesbitt D. Brown
  • Richard K. Gordon
  • Ruthann M. Smejkal

Organizations

  • Walter Reed Army Institute of Research

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  • Biomedical

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  • Chemistry

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