Pressureless Densification of Ceramic Matrix Composites.

Abstract

The project produced a remarkable improvement in our understanding of how ceramic matrix composites densify and how they may be persuaded to reach high density by pressureless sintering. The key factors which hinder the sintering of ceramic matrix composites were determined and an innovative processing method for alleviating the sintering difficulties was developed. The method involves coating the reinforcement phase with a cladding of the matrix by chemical precipitation. The research formed the first reported study in which polycrystalline ceramic matrix composites containing an appreciable volume fraction of a reinforcement phase (up to 35 vol% particles or 25 vol% whiskers) were sintered to full density. The room temperature mechanical properties of the composites fabricated by pressureless sintering of coated powders were significantly better than those for similar composites fabricated from mechanically mixed powders. Pressureless sintering of a ceramic matrix with rigid inclusions was analyzed by a viscoelastic finite element method. The effects of inclusion volume fraction, inclusion shape, inclusion interactions and matrix packing were considered. The model predictions showed good agreement with the experimental data. Considerable potential exists for the application of the experimental and theoretical procedures developed in the project. Ceramic matrix composites, Sintering, Analytical modeling.

Document Details

Document Type
Technical Report
Publication Date
Jul 31, 1993
Accession Number
ADA269137

Entities

People

  • L. R. Dharani
  • M. N. Rahaman
  • R. E. Moore

Tags

DTIC Thesaurus Topics

  • Ceramic Matrix Composites
  • Chemical Precipitation
  • Composite Materials
  • Experimental Data
  • Finite Element Analysis
  • High Density
  • Inclusions
  • Mechanical Properties
  • Precipitation
  • Sintering

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Metallurgy
  • Nanocomposite Materials Science