Scaling Laws for Diamond Chemical Vapor Deposition. Diamond Surface Chemistry

Abstract

A simplified model of the gas-surface chemistry occurring during chemical vapor deposition of diamond thin films is presented. The model results in simple scaling relations, useful for process scale-up and optimization, for growth rate and defect density in terms of the local chemical environment at the substrate. A simple two-parameter expression for growth rate is obtained, which with suitable parameter choices reproduces the results of more detailed mechanisms and experiment over two orders of magnitude in growth rate. The defect formation model suggests that the achievable growth rate at specified defect density scales approximately quadratically with the atomic hydrogen concentration at the substrate.

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Document Details

Document Type
Technical Report
Publication Date
Sep 15, 1993
Accession Number
ADA269874

Entities

People

  • David G. Goodwin

Organizations

  • California Institute of Technology

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Chemical Reactions
  • Chemical Vapor Deposition
  • Chemistry
  • Energy
  • Energy Transfer
  • Equations
  • High Pressure
  • Hydrocarbons
  • Hydrogen
  • Measurement
  • Military Research
  • Molecular Dynamics
  • Rate Of Formation
  • Steady State
  • Substrates
  • Surface Chemistry
  • Vapor Deposition

Readers

  • Combustion science or combustion engineering.
  • Fluid Dynamics.
  • Materials Science and Engineering.