Synthesis and Antimalarial Activity of Some 9-Substituted Artemisinin Derivatives

Abstract

Several 9-substituted derivatives of the antimalarial drug artemisinin have been prepared by functionalizing the double bond-6f artemisitene and related compounds. Stereochemical assignments for these compounds were made using a combination of NMR experiments, an X-ray diffraction study of one compound and chemical correlations of several other compounds with this one compound of unambiguous structure and with its epimer. The compounds synthesized show a wide variation in in vitro antimalarial activity. Antimalarial activity, Artemisitene, Nuclear magnetic resonance, X-Ray diffraction.

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Document Details

Document Type
Technical Report
Publication Date
Aug 20, 1993
Accession Number
ADA270011

Entities

People

  • James M. Karle
  • Nancy Acton
  • Robert E. Miller

Organizations

  • Walter Reed Army Institute of Research

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Abstracts
  • Alcohols
  • Alkanes
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Diffraction
  • Liquid Chromatography
  • Magnetic Resonance
  • Malaria
  • Materials
  • Organic Chemistry
  • Oxygen
  • Resonance
  • Silica Gels
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

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  • Materials Science and Engineering.
  • Molecular and Cellular Biochemistry