Characterization of Vapor Plume Species and Deposition Residues Resulting from Pulsed Laser Ablation of a Graphite/Epoxy Composite

Abstract

A modified time-of-flight mass spectrometer (TOFMS) fitted with a special collection stage for carbon-coated transmission electron microscope specimen grids is used to monitor laser-pulse ablation products from graphite/ epoxy composite targets. Scanning electron microscopy observations show ablation damage to consist of matrix pyrolysis, fiber fracture, and spallation of fragments which include elemental hydrogen, carbon epoxide, and acetylene groups. Transmission electron microscope examination of specimen grids showed a variety of crystals and polycrystalline hexagonal graphites having a wide range of shapes including spheres and faceted polyhedra and platelets, textured flake structures, and microrosettes. These observations lend some credibility to a model for laser-shock and pyrolysis effects which creates molecular plume fragments and deposition fragments of hexagonal graphite.... Graphite/epoxy composite, Laser ablation. Laser shock, Time-of-Flight Mass Spectrometry (TOFMS) , Vapor blow-off, Transmission Electron Microscopy (TEM)

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1993
Accession Number
ADA270101

Entities

People

  • Charles J. Miglionico
  • Charles Stein
  • Kenneth A. Lincoln
  • Larry E. Murr
  • Robert E. Roybal

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Ablation
  • Composite Materials
  • Crystal Structure
  • Crystals
  • Electron Microscopes
  • Electron Microscopy
  • Epoxy Composites
  • Graphitic Materials
  • Materials
  • Microscopes
  • Microscopy
  • Polycrystals
  • Pyrolysis
  • Scanning Electron Microscopes
  • Scanning Electron Microscopy
  • Spectra
  • Strategic Defense Initiative

Fields of Study

  • Physics

Readers

  • Powder metallurgy of Titanium alloys.
  • Pulsed Power and Plasma Physics.
  • Reinforced Composite Materials

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene