Photoluminescence Spectroscopy of Zinc Germanium Diphosphide (ZnGeP2)

Abstract

Zinc germanium diphosphide (ZnGeP2) is a chalcopyrite semiconductor with strong nonlinear optical properties and potential application to Air Force interests. The characteristics of this material have been studied using photoluminescence (PL) spectroscopy. The PL spectrum is dominated by transitions from the conduction band to a deep acceptor level, and features in the spectrum suggest that more than one transition is being observed. The PL is partially polarized, and the degree of polarization appears to differ for each feature in the spectrum. The relative PL intensity of these features are seen to depend upon the wavelength of the excitation source in a fashion which suggests that the observed transitions may originate from three separate conduction bands. These experimentally observed results are found to agree qualitatively with the published band structure of ZnGeP2.

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Document Details

Document Type
Technical Report
Publication Date
Sep 13, 1993
Accession Number
ADA270705

Entities

People

  • Jack E. Mccrae Jr

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Band Gaps
  • Band Structures
  • Conduction Bands
  • Energy Bands
  • Laser Beams
  • Lasers
  • Materials
  • Measurement
  • Optical Properties
  • Optics
  • Quantum Mechanics
  • Semiconductors
  • Spectroscopy
  • Spin-Orbit Interaction
  • Ultraviolet Lasers
  • Waveplates

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Systems Analysis and Design

Technology Areas

  • Microelectronics