Photonics and Nonlinear Optics with Molecular Materials and Polymers

Abstract

We used a multidisciplinary approach to understand the structure- property relationship with an aim towards developing novel second-order and third-order nonlinear materials with enhanced performance for photonics applications. We used a combination of theoretical modeling and experimental measurement of nonlinearities in a group of systematically derivatized structures to understand the structure-property relationship. This approach was extremely useful in designing new structures with enhanced nonlinearities. We have incorporated organic second-order chromophores in sol-gel processed SiO2 and TiO2 composites which have been successfully electrically poled to form stable aligned structures. In-situ poling studies while monitoring second harmonic generation and electro-optic modulation were used to study the poling dynamics. The microstructures of sol-gel processed composites were investigated. A combination of optical Kerr-gate, transient absorption and degenerate four- wave mixing was used along with appropriate theoretical development to understand the nature of resonant third-order optical nonlinearity.

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Document Details

Document Type
Technical Report
Publication Date
Feb 28, 1993
Accession Number
ADA271747

Entities

People

  • Paras Nath Prasad

Organizations

  • State University of New York at Albany

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Composite Materials
  • First Principles Calculations
  • Materials
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Nonlinear Optics
  • Optical Materials
  • Optical Properties
  • Optics
  • Organic Materials
  • Polymeric Films
  • Refractive Index
  • Wave Mixing

Readers

  • Materials Science and Engineering.
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.