Electronically Metastable Molecules of High Symmetry

Abstract

This project is part of the search for a novel propellant based on molecules with excess internal energy for use in the combustion process. Spectroscopic properties of neutral molecules of triatomic hydrogen, tetraoxygen, superexcited oxygen, and hydronium were investigated using laser ionization, laser photodissociation, and charge neutralization techniques. The neutrals were prepared in a fast beam by electron transfer from stationary gas targets to mass selected ions. Excited state lifetimes and electronic, vibrational, and rotational-structures were examined as well as the dissociation products and the effect that external electric fields have on the stability of the molecules.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
May 01, 1993
Accession Number
ADA272015

Entities

People

  • Hanspeter Helm

Organizations

  • SRI International

Tags

DTIC Thesaurus Topics

  • Air Force
  • Dissociation
  • Dye Lasers
  • Electron Transfer
  • Electrons
  • Insensitive Explosives
  • Ionization
  • Laser Beams
  • Measurement
  • Metastable State
  • Molecular Physics
  • Molecules
  • Physics Laboratories
  • Quantum Mechanics
  • Spectra
  • Spectroscopy
  • Spin-Orbit Interaction

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics

Technology Areas

  • Directed Energy
  • Microelectronics