Isothiazolone Volatility Study of a Water Bottom from Fuel Treated with Kathon(trade name) FP1.5 Biocide

Abstract

An analytical method based on the gas chromatographic/mass spectrometry separation and detection of the two isothiazolones (5-chloro-2- methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one), the active ingredients in one commercially available biocide used to treat fuel systems contaminated with microbiological growth, is described. A modification of this method, to allow static headspace detection of these isothiazolones, is also described. Results of experiments using the modified technique demonstrated that these two compounds do not volatilize from a sea water solution at temperatures up to 70 deg C. This suggests that un-depleted isothiazolone in the water bottom, of fuel tanks treated with Kathon FP1.5 biocide, would not volatilize into the habitable air space above the bilge to generate toxic components that could then be inhaled by the personnel working in the immediate vicinity. Microbiological Contamination, Isothiazolone, Kathon FPI.5, Headspace Analysis.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1993
Accession Number
ADA273165

Entities

People

  • R. D. Haggett
  • Richard M. Morchat

Organizations

  • Defence Research and Development Canada

Tags

Communities of Interest

  • Biomedical
  • Human Systems

DTIC Thesaurus Topics

  • Animals
  • Aqueous Solutions
  • Birds
  • Contamination
  • Detection
  • Detectors
  • Fish
  • Fuel Systems
  • Fuel Tanks
  • Fungi
  • Gases
  • Management Personnel
  • Mass Spectrometry
  • Rodents
  • Sea Water
  • Spectrometry
  • Water

Readers

  • Analytical Chemistry
  • Environmental Engineering

Technology Areas

  • Space