LPCVD of InN on GaAs(110) Using HN3 and TMIn: Comparison with Si(100) Results

Abstract

Low-pressure chemical vapor deposition (LPCVD) of InN and laser- assisted LPCVD on GaAs(110) and Si(100) using HN3 and trimethyl indium (TMIn) has been studied with XPS, UPS and SEM. Without 308-nm excimer laser irradiation, InN film was built on the GaAs but not on Si surface under the present low-pressure conditions. When the photon beam was introduced, InN films with In:N atomic ratio of 1.0 + or - 0. 1 and a thickness of more than 20 A (the limit of the electron escaping depth for the In3d X-ray photoelectrons) were formed on Si(100) surface. In both cases, the formation of surface nitrides at the initial film growth processes was clearly indicated in the XP spectra. The He(II) UP spectra taken from InN films on GaAs and Si are nearly identical and agree well with the result of a pseudo-potential calculation for the InN valence band. The corresponding SEM pictures showed smooth InN films on GaAs(110), while grains with diameter of approx. 100 nm were observed for InN on Si(100).

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Document Details

Document Type
Technical Report
Publication Date
Dec 07, 1993
Accession Number
ADA273555

Entities

People

  • Lin Ming-chang
  • Yuheng Bu

Organizations

  • Emory University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemistry
  • Electron Microscopy
  • Electrons
  • Energy Bands
  • Films
  • Laser Diodes
  • Lasers
  • Materials
  • Military Research
  • Optoelectronic Devices
  • Photoelectrons
  • Scanning Electron Microscopy
  • Semiconductor Lasers
  • Semiconductors
  • Spectra
  • Spectroscopy
  • Valence Bands

Fields of Study

  • Materials science

Readers

  • Molecular Photonics/Laser Physics
  • Mycotoxin ecology in Amazonian ecosystems.
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene