A Preliminary Evaluation of the Phosphazene Resin PPZ

Abstract

A phosphazene material, PPZTM, is reported by Idemitsu Petrochemical Company (Tokyo, Japan) to have excellent chemical and abrasion resistance properties for hardcoating applications. An evaluation of the chemical resistance of this coating is presented. PPZ coated on poly(ethylene terephthalate) (PET) films were challenged with simulants (2-chloroethyl ethyl sulfide (CEES), 2-chloroethyl methyl sulfide (CEMS), diisopropyl methyphosphonate (DIMP)) and a decontaminant (DS-2) via a droplet test method. Preliminary results showed that the PPZ coating was affected by DIMP, CEES, and CEMS as observed by optical and scanning electron microscopy, (SEM). Upon visual examination, the DS-2 treated specimen did show an effect; however, the coating's behavior to this corrosion liquid is inconclusive. In addition, PPZ(TM) resin was coated on polycarbon (PC) using a modified ASTM D823-87 method and cured by ultraviolet light. Curing time was determined by Fourier transform infrared spectroscopy (FTIR) using an attenuated total reflectance (ATR) technique. The Taber abrasion resistance of the PPZ-coated PC specimens were slightly lower than reported values. Phosphazene, Chemical resistance, Polyethylene terephthalate, Polycarbonates, Abrasion.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1993
Accession Number
ADA273674

Entities

People

  • Adam J. Jaglowski
  • Karim M. Gabriel
  • Marc S. Pepi

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Alkenes
  • Chemistry
  • Dacron
  • Electron Microscopy
  • Films
  • Materials
  • Materials Science
  • Materials Testing
  • Military Research
  • Optical Properties
  • Resins
  • Resistance
  • Scanning Electron Microscopy
  • Spectra
  • Test Methods
  • Wear Resistance

Fields of Study

  • Materials science

Readers

  • Neurotoxicology
  • Polymer Science and Technology
  • Surface Coatings Technology.

Technology Areas

  • Microelectronics