Pseudomorphic Semiconducting Heterostructures from Combinations of AIN, GaN and Selected SiC Polytypes: Theoretical Advancement and its Coordination with Experimental Studies of Nucleation, Growth, Characterization and Device Development

Abstract

Thin epitaxial films of SiC/AlN multilayers and (AlN)x(SiC)1-x solid solutions have been grown by plasma-assisted, molecular beam epitaxy between 1050-1300 deg C using the gas sources Of Si2H6, C2H4 and N2, the last decomposed using a compact electron cyclotron resonance plasma source, and the solid source of Al. Vicinal alpha(6H)-SiC(0001) was used for the substrates. Electron diffraction and high resolution TEM revealed monocrystalline layers and pseudomorphic growth. Additional studies have shown that (1) the off-axis orientation of the substrate affects the film morphology, (2) surface cleaning is very important and (3) Si/C gas flow ratios may be used to control the SiC polytype. Both Beta(3C)- and alpha(6H)-SiC have been successfully deposited on alpha(6H)-SiC substrates. The chemical interdiffusion between monocrystalline AlN films and alpha(6H)-SiC wafers is also under study. The results of the successful research regarding multilayer heterostructures in the AlN/GaN system are now being used to guide the fabrication of a double heterostructure ultra- violet light emitting diode based on suitably doped AlGaN confinement layers with improved carrier confinement and mobility.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1993
Accession Number
ADA274247

Entities

People

  • K. Linthicum
  • Robert F Davis
  • S. Kern
  • S. Roberson
  • Shuta Tanaka

Organizations

  • North Carolina State University

Tags

DTIC Thesaurus Topics

  • Band Gaps
  • Chemical Vapor Deposition
  • Chemistry
  • Compound Semiconductors
  • Electronics Laboratories
  • Electrons
  • Fabrication
  • Heterojunctions
  • Light Emitting Diodes
  • Materials
  • Materials Science
  • Molecular Beam Epitaxy
  • Optoelectronic Devices
  • Quantum Wells
  • Semiconductor Devices
  • Semiconductors
  • Silicon Carbide

Fields of Study

  • Materials science

Readers

  • Nanofabrication and Microfabrication.
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene