X-Ray Crystal Structures of ((Me3SiCH2)2InCl)2 and ((Me3SiCH2)InCl2)

Abstract

The use of alternative group 13 and group 15 compounds to fabricate traditional 13-15 materials has received great attention over the past decade. Indeed, fundamental chemistry involving the structure, bonding, and reactivity of such species has been of primary concern in our laboratory for some time. It is our belief, that through these investigations a better understanding can be obtained as to the factors that influence and dictate the reactivity of these species. Herein we report the solid-state structures of (Me3SiCH2)2InCl2 (I) and (Me3SiCH2)InCl2 (infinity) (II) which have been found to be dimeric and polymeric, respectively.

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Document Details

Document Type
Technical Report
Publication Date
Jan 18, 1994
Accession Number
ADA275074

Entities

People

  • Andrew T. McPhail
  • Leonidas J. Jones Iii.
  • Mark F. Self
  • Richard L. Wells

Organizations

  • Duke University

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Atmospheres
  • Chemical Laboratories
  • Chemistry
  • Chlorine
  • Civil Engineering
  • Controlled Atmospheres
  • Crystal Structure
  • Crystals
  • Geometry
  • Glass Fibers
  • Hydrogen
  • Military Research
  • Single Crystals
  • Surface Warfare
  • United States
  • X Rays

Fields of Study

  • Chemistry
  • Materials science

Readers

  • Organic Chemistry
  • Systems Analysis and Design