Infrared Fiber Optic Diagnostic Observations of Solid Propellant Combustion

Abstract

We report on work to develop and demonstrate a diagnostic technique using infrared fiber optics to probe the decomposition processes in burning gun propellant strands. The experiments reported here involve measuring the absorption across an open gap between two embedded fibers as it fills with gaseous decomposition products. Spectroscopic detection is achieved using pairs of bandpass filters. The absorption record can be correlated with readings from embedded thermocouples and with a high resolution video recording of the burn. We have observed N20, a decomposition product of RDX, evolving into the observation volume. The N20 appearance is often an abrupt event. Coupled with evidence that it can occur while the observation region is relatively cool and far from the burning surface (observed in cases involving burning at 6 atm pressure), these observations suggest hypotheses concerning the physical processes in the condensed phases of this propellant, hypotheses including the development of pressurized voids or matrix-trapped bubbles which can release decomposition gases into the unburnt propellant through suddenly opening cracks. The appearance of N20 after the temperature record suggests that melting and decomposition of RDX have begun (observed in 1 atm cases) implies that N20 formation is indeed not an initial step in RDX decomposition under our conditions. Solid propellant combustion, Infrared fiber optic absorption diagnostic.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1993
Accession Number
ADA276061

Entities

People

  • C. E. Kolb
  • J. Wormhoudt
  • P. L. Kebabian

Organizations

  • Aerodyne Research

Tags

Communities of Interest

  • Advanced Electronics
  • Weapons Technologies

DTIC Thesaurus Topics

  • Burning Rate
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Composite Propellants
  • Decomposition
  • Heat Transfer
  • Mass Spectrometry
  • Materials Laboratories
  • Materials Science
  • Measurement
  • Military Research
  • Propellants
  • Solid Phases
  • Solid Propellants
  • Spectra

Fields of Study

  • Physics

Readers

  • Combustion and Flow Dynamics.
  • Materials Science and Engineering.
  • Quantum Chemistry