Silicone Grease as a Precursor to a Pseudo Crown-Ether Ligand: Crystal Structure of (K+)3K(Me2SiO)7+)(HIn(CH2CMe3)3-)4

Abstract

The crystallization of K((HIn(CH2CMe3)3) from heptane in the presence of silicone grease led to the formation of the title compound, in which one potassium cation is surrounded by a planar cyclo-(Me2SiO)7 ligand; K+...O distances range from 2.86(3) to 2.99(4)A. Indium-hydride, Silicon-oxygen crown ether, X-ray structural study.

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Document Details

Document Type
Technical Report
Publication Date
Feb 25, 1994
Accession Number
ADA276343

Entities

People

  • Charles H. Lake
  • Melvyn Rowen M.R. Churchill
  • O. T. Beachly Jr.
  • Sun-hua L. Chao

Organizations

  • University at Buffalo

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemistry
  • Crown Ethers
  • Crystal Structure
  • Crystals
  • Diffraction
  • Diffractometers
  • Ethers
  • Materials
  • Military Research
  • New York
  • Physical Properties
  • Precursors
  • United States
  • United States Government
  • Universities
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

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