Synthesis, Characterization and Molecular Structure of a Compound with a Ring of Group 13, 15 and 16 Atoms (Me3CCH2)2InP(t-Bu)2In(CH2CMe3)2SePh

Abstract

The compound (Me3CCH2)2InP(t-Bu)2In(CH2CMe3)2SePh has been prepared from equimolar quantities of (Me3CCH2)2InP(t-Bu)22 and (Me3CCH2)2InSePh2 in pentane solution, recrystallized and fully characterized. This mixed-bridge organoindium species crystallized in the centrosymmetric space group P(bar)1 (No. 2) with a gamma 10.069(2)A, b = 11.627(4)A, c = 18.452(4)A, alpha = 100. 74(2)deg, Beta = 99.33(2), gamma = 103.38(2)deg, V = 2016.9(8)A(svp)3, and Z = 2.

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Document Details

Document Type
Technical Report
Publication Date
Feb 25, 1994
Accession Number
ADA276584

Entities

People

  • Charles H. Lake
  • Melvyn Rowen M.R. Churchill
  • O. T. Beachley Jr.
  • Sun-hua L. Chao

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  • University at Buffalo

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  • Air Platforms

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  • Chemical Compounds
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  • Chemistry

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  • Organic Chemistry

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