Electron Detachment Reactions of Fluorinated Carbanions with Atomic Hydrogen

Abstract

The gas phase reactions of CF3-, C2F5-, and C3F3- with atomic hydrogen have been studied at 300 K using a selected ion flow tube (VT-SIFT) instrument. In addition, reactions of these ions with molecular hydrogen were studied. The reactions with atomic hydrogen are all fast but below collisional efficiency. These ions do not react measurably with H2. The products of the reactions with atomic hydrogen include free electrons since no ionic products were detected in any of the reactions with H. Electron detachment, Ion-molecule, Kinetics, Fluorocarbon.

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Document Details

Document Type
Technical Report
Publication Date
Jan 15, 1994
Accession Number
ADA276614

Entities

People

  • Albert A Viggiano
  • John F. Paulson
  • Robert A. Morris

Organizations

  • Phillips Laboratory

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Acids
  • Chemistry
  • Efficiency
  • Electrons
  • Flow Rate
  • Free Electrons
  • Heat Of Formation
  • Hydrogen
  • Instrumentation
  • Ion Sources
  • Ions
  • Kinetics
  • Mass Spectrometers
  • Measurement
  • Molecules
  • Nose Cones
  • Spectrometers

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Irregular Warfare and Special Operations Cyberspace Operations against Adversarial Threats.
  • Organic Chemistry

Technology Areas

  • Microelectronics