ESDIAD Study of Step Site Bonding on a Vicinal Si(100) Surface Upon Cl2 Adsorption

Abstract

Characteristic chlorine bonding sites have been detected on a vicinal Si(100) single crystal surface exposing Si(100) terraces. 7-8 Si atoms in width. These terraces are separated by 2-atom layer height steps. Following annealing to 673 K. three C1+ beams are observed by the electron stimulated desorption ion angular distribution (ESDIAD) method. Two of the C1+ beams originate from silicon-dimer dangling bond sites on the Si(100) terraces. The third C1+ beams is associated with the Si-C1 bond on the step sites. and it emits Cl+ at a polar angle of 24 +/1 deg with respect to the <100> direction. in the downstairs direction. The direction of Cl+ emission from the step site is qualitatively consistent with the theoretical model of the step reconstruction proposed by Chadi. Chlorine, Step sites, Si(100), Vicinal, Etching.

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Document Details

Document Type
Technical Report
Publication Date
Feb 14, 1994
Accession Number
ADA277029

Entities

People

  • J. T. Yates Jr.
  • Qing Gao
  • Wolfgang J. Wolfgang J. Choyke
  • Z. Dohnalek

Organizations

  • University of Pittsburgh

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  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemistry
  • Computer Science
  • Computer Simulations
  • Desorption
  • Detectors
  • Electron Energy
  • Electronic Mail
  • Electrons
  • Emission
  • Energy
  • Kinetic Energy
  • Materials
  • Materials Science
  • Measurement
  • Simulations
  • Spectroscopy
  • Three Dimensional

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  • Electrochemical Engineering/ Fuel Cell Technologies
  • Organic Chemistry

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  • Microelectronics
  • Microelectronics - Graphene