Group 12 Thiolates: Syntheses, Characterization and Decomposition Pathways

Abstract

Zinc- and cadmium bis(alkylthiolate) compounds have been prepared and converted into the appropriate binary metal sulfides by thermal treatment. Several mercury chlorothiolates have been synthesized and characterized by single crystal X-ray diffraction. Their decomposition pathways are discussed. The prepared binary metal sulfides have been studied by XRPD and in selected cases - by particle size determination. The volatile co-products have been isolated and characterized by GC/MS. Group 12 thiolates, Metal sulfides, Decomposition pathways.

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Document Details

Document Type
Technical Report
Publication Date
Mar 08, 1994
Accession Number
ADA277055

Entities

People

  • Bernhard Neumuller
  • Gertrud Krauter
  • Virgil L. Goedken
  • William S. Rees Jr.

Organizations

  • Georgia Tech

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Biochemistry
  • Chemical Synthesis
  • Chemistry
  • Compound Semiconductors
  • Engineering
  • Equations
  • Materials
  • Materials Science
  • Military Research
  • Particle Size
  • Particles
  • Schools
  • Single Crystals
  • United States
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Organic Chemistry
  • Surface Engineering/Surface Coating Technology.