Influence of Trace Components on the Viscoelastic Properties of a Polymer Solution

Abstract

Research on characterization of viscoelastic properties of ultrahigh molecular weight polymer solutions led to the discovery of variations in rheological properties combined with variable dissolution behavior for certain polymer-liquid systems. The reference solutions exhibited extreme intra sample variations; therefore, the influence of processing and trace impurities on rheological property variance was studied. Measurements of first normal stress difference, apparent viscosity, and dynamic viscoelastic properties were performed as a function of controlled addition of components with specific molecular interactions with polymers or solvents (e.g., various salts, surfactant, and chelating reagents). In addition, processing treatments such as filtration and centrifugation were applied and their influence on rheological properties of the polymer solution was determined. Rheology, Viscoelasticity, Additives, Apparent viscosity, Polymer solution, First normal stress difference

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1993
Accession Number
ADA277171

Entities

People

  • Seok H. Hong
  • Wendel J. Shuely

Organizations

  • Edgewood Chemical Biological Center

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Alkenes
  • Benzoic Acids
  • Carboxylic Acids
  • Chemistry
  • Copolymers
  • Engineering
  • Filtration
  • Hydrogen Bonds
  • Impurities
  • Materials
  • Measurement
  • Molecular Weight
  • Polymer Degradation
  • Polymers
  • Solid Phases
  • Solubility
  • Viscosity

Readers

  • Coastal Oceanography
  • Environmental Engineering
  • Materials Science and Engineering.