Evaluation of a Hyperbaric System to be Used in Conjunction with a Fluorometer

Abstract

A high-pressure chamber that can be used inside the sample chamber of a spectrofluorometer is described and some performance characteristics are presented. The chamber body, constructed of 316 stainless steel, is temperature regulated using resistive heating elements and a microprocessor-based proportional integral derivative controller. The chamber holds a standard 1-sq cm cuvette that indexes with an electromagnetic stirrer. Injection of different solutions into the closed and pressurized (6.8 MPa) vessel is accomplished by computer-controlled, low-volume solenoids attached to separate microliter injection ports. Repetitive injections of fluids down to a volume of 7 microliters are possible in the pressurized chamber. Temperature stability of the chamber is + or - 0.2 deg C at atmospheric or elevated pressure. However, during the initial phase (first 3 min) of pressurization, at a compression rate of 0.62 MPa/min, a 0.23 deg C/min increase in temperature occurs. The chamber windows depress the relative intensity of the emitted light by approximately 20% for visible light and 40% for near UV; however, total sensitivity of the system is sufficient to accomplish most determinations while maintaining a good signal- to-noise ratio. This system can be used to evaluate the response of several molecular and cellular events during compression and at depth with the use of various fluorometric probes.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1993
Accession Number
ADA277749

Entities

People

  • J. S. Colton
  • Katherine E. Miller
  • S. L. Pocotte
  • Y. Grossman

Organizations

  • Naval Medical Research Center

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Back Pressure
  • Biomedical Research
  • Cells
  • Chambers
  • Compression
  • Fluids
  • High Pressure
  • Hyperbaric Chambers
  • Hyperbaric Medicine
  • Liquid Chromatography
  • Maryland
  • Optical Materials
  • Pressure Regulators
  • Pressurization
  • Solenoids
  • Stainless Steel
  • Test And Evaluation

Readers

  • Analytical Chemistry
  • Internal Combustion Engine (ICE) Technology.
  • Thermal Physics or Thermal Science.