Isolated So(4)-2 and PO(4)-3 Anions Do Not Exist

Abstract

Ab initio theoretical methods that incorporate effects of orbital relaxation and electron correlation are used to examine the possibility that doubly or triply charged oxy-anions of the class S04-2, SeO4-2, TeO4-2, or P04- 3, AsO4-3, SbO4-3 are stable relative to electron detachment in the absence of any surrounding medium. In all of these cases, our findings indicate quite clearly that these multiply charged oxyanions are not stable.

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Document Details

Document Type
Technical Report
Publication Date
Apr 22, 1994
Accession Number
ADA278831

Entities

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  • Alexander I. Boldyrev
  • Jack Simons

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  • University of Utah

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  • Energy and Power Technologies

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  • Abstracts
  • Charged Particles
  • Chemistry
  • Electronic States
  • Electronic Structure Theory
  • Electrons
  • Elementary Fermions
  • Free Electrons
  • Frequency
  • Geometry
  • Mass Spectrometry
  • Military Research
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  • Perturbation Theory
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  • United States
  • United States Government

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