New Organometallic Polymeric Materials: The Search for X(2) NLO organometallic Polymers.

Abstract

A brief overview of organometallic X(2) nonlinear optical (NLO) polymers is presented. The synthesis of new ferrocene NLO-phores is presented along with their copolymerization with methyl methacrylate to generate organometallic NLO-polymers (NLOPs). A new class of organometallic NLO-phores were synthesized by condensation of ferrocene-carboxaldehyde with fluorene compounds. The fluorenyl-ferrocene NLO-phores displayed interesting linear optical properties and reactivity. NLO-spectroscopy was employed to study the orientation and relaxation behavior of the new organometallic NLOPs and we report on these interesting results. NonLinear Optical, Corona Poling, Organometallic Polymers, Ferrocene

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Document Details

Document Type
Technical Report
Publication Date
May 28, 1994
Accession Number
ADA280197

Entities

People

  • Brooks Cochran
  • Edward G. Toplikar
  • Hilary S. Lackritz
  • John T. Kerney
  • Michael E. Wright

Organizations

  • Utah State University

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms

DTIC Thesaurus Topics

  • Alkynes
  • Chemical Analysis
  • Chemical Compounds
  • Chemical Engineering
  • Chemical Reactants
  • Chemical Synthesis
  • Chemistry
  • Copolymers
  • Ferrocenes
  • Inorganic Materials
  • Macromolecules
  • Metals
  • Optical Properties
  • Organic Chemistry
  • Organic Materials
  • Polymers
  • Transition Metals

Fields of Study

  • Chemistry

Readers

  • Polymer Science and Technology