Nitride Semiconductors for Ultraviolet Detection

Abstract

Monocrystalline GaN thin films have been grown on vicinal alpha(6H)- SiC(0001) and sapphire(0001) wafers via organometallic vapor phase epitaxy (OMVPE) using a cold-wall, vertical barrel reactor with triethylgallium (TEG) and ammonia. Chemical, analytical and microstructural studies revealed epitaxial films of high microstructural quality. The surface morphologies and photoluminescence spectroscopy (PL) spectra of GaN films on both substrates are presented and described. Specifically, the PL data revealed donor bound exciton emission at 357.6nm for films thicker than 1 mm. Two other emission peaks at 375-378 nm and 540 nm were common to all films tested. Hall effect measurements showed that the unintentionally doped films were highly n-type with a mobility of approx. 40 sq cm/V(dot)s. The new method for the growth of the III-V compounds, namely, the use on an ammonia cracker cell to minimize film damage and increase growth rate has been designed and ordered. Preliminary studies of the use of AlN as a candidate insulator material has been conducted via the fabrication of an MIS structure. I-V and high frequency C-V measurements revealed a 13.4 MV/cm breakdown field and a dielectric constant of approx. 14. Operation of the MIS devices at 300 deg C with only a slight reduction in the breakdown field to 13 MV/cm.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1994
Accession Number
ADA280988

Entities

People

  • Bradley T. Perry
  • C. Wang
  • K. Linthicum
  • Robert F Davis
  • W. Weeks

Organizations

  • North Carolina State University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Band Gaps
  • Chemical Vapor Deposition
  • Chemistry
  • Compound Semiconductors
  • Dielectric Permittivity
  • Dielectric Properties
  • Dielectrics
  • Energy Bands
  • Hall Effect
  • Luminescence
  • Materials
  • Materials Science
  • Measurement
  • Semiconductors
  • Silicon Carbide
  • Spectroscopy
  • Thin Films

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene