Chemoselective Reactions of a-Aminonitriles.

Abstract

A carbocyclic model for 4-anilino-4-cyano-l-benzylpiperidine was used to elucidate the chemistry of the reaction with diisobutylaluminum hydride. Reactions with alkaline hydrogen peroxide, triethyloxonium tetrafluoroborate and boron trifluoroetherate in methanol were studied for possible chemoselectivity for the cyano as opposed to the anilino function. Aminonitriles, DIBAL-H, Lewis acids.

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1994
Accession Number
ADA282578

Entities

People

  • Harold D. Banks
  • Morris A. Waugh

Organizations

  • Edgewood Chemical Biological Center

Tags

DTIC Thesaurus Topics

  • Acids
  • Alcohols
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Hydrogen
  • Lewis Acids
  • Methanols
  • Organic Chemistry
  • Peroxides
  • Rocket Oxidizers

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry