Investigation of Compact Layers at a Liquid/Liquid Interface

Abstract

The two objectives of this project are: (1) to utilize the atomic resolution provided by the scanning tunneling microscope (STM) to obtain molecular information about molecules adsorbed on liquid surface; and (2) to provide a compression/expansion micro-Langmuir Blodgett system. Standard techniques for studying liquid surfaces only describe the average behavior of large numbers of molecules. The STM may supply molecular-scale information about the electronic structure of a liquid surface if the molecules of interest are immobilized into a two-dimensional crystal. We have studied the mercury/air interface as a function of adsorbate surface pressure using a mercury sessile drop that can be expanded and contracted using a digitially controlled microliter syringe (Molecular Vise system). The added feature of this arrangement is the ability to control precisely the volume and, thus, the surface area of the sessile mercury drop.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Apr 27, 1993
Accession Number
ADA283949

Entities

People

  • Jiri Janata

Organizations

  • University of Utah

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Control Systems
  • Electrodes
  • Films
  • Frequency
  • Materials
  • Materials Science
  • Measurement
  • Molecular Electronics
  • Monomolecular Films
  • Optical Properties
  • Phase
  • Phase Transformations
  • Thin Films
  • Transitions
  • Two Dimensional
  • United States
  • Vapor Deposition

Fields of Study

  • Chemistry
  • Physics

Readers

  • Image Processing and Computer Vision.
  • Quantum Chemistry
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene