Excited State Chemistry of PF, NF, and NCl

Abstract

The objective of our research program is to develop gas phase, chemically driven, energy storage systems that can serve as the media for short wavelength, electronic-transition lasers. We have selected the PF, AsF, and NF molecules for study, because of the success in the chemical generation and utilization of the excited singlet states of 02 in the oxygen-iodine laser. Our goals are to develop laboratory sources of the singlet states of PF and AsF and to characterize these states. We also wish to develop chemical sources of these molecules and then to utilize this stored energy, perhaps by energy-pooling reactions, to form a suitable upper laser state. Our laboratory already has considerable experience with the chemistry of the NF system. Unfortunately, NF(a) has not been successfully coupled to an acceptor state (other than perhaps I Atoms) to build a laser

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Document Details

Document Type
Technical Report
Publication Date
May 14, 1993
Accession Number
ADA285224

Entities

People

  • D. W. Setser

Organizations

  • Kansas State University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Atoms
  • Chemical Oxygen Iodine Lasers
  • Chemical Reactions
  • Chemistry
  • Demographic Cohorts
  • Electro-Optics
  • Electronic States
  • Emission Spectra
  • Energy
  • Energy Storage
  • Laser Applications
  • Lasers
  • Metastable State
  • Molecules
  • Quantum Properties
  • Spectroscopy
  • Spin-Orbit Interaction

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics
  • Software Engineering.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Microelectronics