Mass Spectral Data of Alkyl and Cycloalkyl Methylphosphonofluoridates

Abstract

Electron impact (EI) mass spectra of over 60 alkyl and cycloalkyl methylphosphonofluoridates (alkyl/cycloalkyl < or = to C10) were recorded and taken up in databases. Each compound was prepared in situ by mixing an alcohol with methylphosphonodifluoride followed by gas chromatographic-mass spectrometric analysis (GC-MS) of the reaction mixture. The choice of the alcohols was restricted to relatively inexpensive, primary and secondary alcohols. the EI mass spectra and a short description of the fragmentation patterns of the methylphosphonofluoridates are presented.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1994
Accession Number
ADA285312

Entities

People

  • A. L. De Long
  • E. R. Wils

Organizations

  • Prins Maurits Laboratorium TNO

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Alcohols
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemical Weapons
  • Chemistry
  • Chlorides
  • Databases
  • Fatty Acids
  • Fragmentation
  • G Agents
  • Mass Spectra
  • Mass Spectrometry
  • Mass Spectroscopy
  • Spectra
  • Spectrometry
  • Spectroscopy

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Systems Analysis and Design

Technology Areas

  • Microelectronics