Synthesis and Structure of a Novel Bis-Stibole

Abstract

The novel benzobis(stibole) 2a, synthesized from bis(zirconacycle) 1, crystallizes to place all three ring substituents in a syn orientation. Complex 2a stacks in such a manner so that the central phenyl ring of two adjacent Sb2C10 ring systems are nearly perfectly eclipsed. (Author)

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Oct 18, 1994
Accession Number
ADA286345

Entities

People

  • Benjamin P. Warner
  • Donald P. Hsu
  • Richard A. Fisher
  • Stephen L. Buchwald
  • William M. Davis

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Antimony
  • Chemical Laboratories
  • Chemistry
  • Crystal Structure
  • Crystals
  • Cyclic Compounds
  • Isomers
  • Materials
  • Military Research
  • New York
  • Ocean Surveillance
  • Orientation (Direction)
  • Surface Warfare
  • United States
  • United States Government
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

  • Aerospace Research.
  • Organic Chemistry