Molecular Spectra and Dynamics at Interfaces.

Abstract

The purpose of the project is to develop a theory of molecular spectra and dynamics of species adsorbed at solid interfaces, in order to provide insight into the properties of interfaces starting from their molecular structure. An additional goal is to develop computational tools to do quantitative calculations of spectroscopic and dynamical quantities. The theoretical and computational tools are developed recognizing that advanced light sources such as tunable lasers, and synchrotron radiation and pulsed lasers provide important tools in the study of solid surfaces to excite adsorbed molecules and to dissociate bonds of adsorbates. Photoelectron spectroscopy (PBS) probes the electronic structure of adsorbed species and also, by comparison to free molecules, provides information on the electronic structure of the solid substrate. Photoinduced desorption (PID) provides information on the strengths of chemical bonds and of Van der Waals forces at surfaces. (jg)

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Document Details

Document Type
Technical Report
Publication Date
Dec 15, 1994
Accession Number
ADA289779

Entities

People

  • David A. Micha
  • N. Y. Ohrn

Organizations

  • University of Florida

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Atomic Orbitals
  • Atoms
  • Charge Transfer
  • Chemical Bonds
  • Chemistry
  • Collisions
  • Desorption
  • Electron Density
  • Electron Transfer
  • Electrons
  • Lasers
  • Light Sources
  • Pulsed Lasers
  • Quantum Mechanics
  • Spectra
  • Spectroscopy
  • Synchrotron Radiation

Fields of Study

  • Physics

Readers

  • Quantum Chemistry
  • Software Engineering.
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Microelectronics