Photogenerated Amines in Polymer Curing and Imaging: Design and Synthesis of (3', 5'- Dimethoxybenzoinyl)oxycarbonyl Carbamates as Novel Photoprecursors of Amines.
Abstract
The design of novel compounds that can be used to photogenerate amines when subjected to UV irradiation is explored. These novel compounds are dimethoxybenzoinyl)oxy carbonyl carbamates that undergo a light induced photocyclization with release of a free primary or secondary amine. The novel photogenerators can be used with 250-350 nm light in a process that is essentially free of side-reactions. These carbamate photogenerators of base may be useful both in polymer curing and imaging processes, and as protecting groups in organic synthesis. (jg)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 20, 1995
- Accession Number
- ADA289945
Entities
People
- C. G. Willson
- James F. Cameron
- Jean Fréchet
Organizations
- Cornell University