Embedded Infrared Fiber Optic Absorption Studies of Nitramine Propellant Strand Burning.

Abstract

We report on continued work to develop and demonstrate the use of infrared fiber optics to probe the decomposition processes in burning gun propellant strands. Our experiments involve measuring the absorption across an open gap between two embedded fibers as it fills with gaseous decomposition products. Several improvements have been made to the experimental technique. In the most significant, detection techniques for the nitrogen oxide species NO2 and NO have been added to the N2O detection system developed in earlier work. O2 detection was accomplished by differential absorption of red and green HeNe lasers, while NO detection used a tunable infrared diode laser. We have observed N2O, NO2 and NO evolving into the observation volume during the burning of an RDX-based composite propellant. Observations to date indicate that NO appears at similar times as N2O, that is, while the observation region is relatively cool and far from the burning surface, while NO2 can significantly precede both NO and N2O. These data will provide additional information on the physical and chemical processes in the condensed phases of this composite propellant. (MM)

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Document Details

Document Type
Technical Report
Publication Date
Nov 04, 1994
Accession Number
ADA290497

Entities

People

  • C. E. Kolb
  • J. Wormhoudt
  • P. L. Kebabian

Organizations

  • Aerodyne Research

Tags

Communities of Interest

  • Advanced Electronics
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Acquisition
  • Burning Rate
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Composite Materials
  • Composite Propellants
  • Data Acquisition
  • Detection
  • Helium Neon Lasers
  • Laser Diodes
  • Lasers
  • Light Sources
  • Measurement
  • Observation
  • Optics
  • Solid Propellants

Fields of Study

  • Physics

Readers

  • Agricultural Chemistry/Soil Science
  • Optical Physics and Photonics.
  • Reinforced Composite Materials

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers