Transitions in Liquid Crystals Initiated with Circularly Polarized Light.

Abstract

The fundamental goal of this research is the discovery of new means to control the physical and optical properties of liquid crystals with light. In work on this project we focused on the development of chiroptical triggers designed to induce a reversible nematic to cholesteric transition in a liquid crystal under the influence of circularly polarized light. Three classes of systems were investigated -- biaryl chromophores, axially symmetric benzylidene cyclohexanes, and chiral cycloheptatrienes. None of these compounds meet all of the requirements for a chiroptical trigger, but the knowledge gained enables a clearer definition of the properties a successful trigger must possess. (jg)

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1994
Accession Number
ADA290525

Entities

People

  • Gary Schuster

Organizations

  • University of Illinois Urbana–Champaign

Tags

Communities of Interest

  • C4I
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Chromophores
  • Crystals
  • Cyclic Hydrocarbons
  • Cycloalkanes
  • Cyclohexanes
  • Hydrocarbons
  • Laser Spectroscopy
  • Liquid Crystals
  • Molecules
  • Optical Properties
  • Organic Chemistry
  • Reversible
  • Spectra
  • Transitions

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Organic Chemistry
  • Systems Analysis and Design