Theories of the Nonlinear Optical Properties of Composite Media: Applications to Phthalocyanine Dyes.

Abstract

This report describes the results of a theoretical investigation into the nonlinear optical response of granular composites. In particular, we have investigated the degree to which the cubic nonlinear response can be enhanced in such composites, relative to the same response in pure materials. Cubic nonlinear response is potentially of great practical importance in developing novel materials with a strongly intensity-dependent transmission coefficient, index of refraction, etc. We find that there are many types of composite geometries which give rise to such strong enhancements. These include composites near the percolation threshold, composites in which one of the components is arranged in the form of a fractal cluster, and nonlinear coatings (such as dyes) adsorbed onto the surface of particles which have a resonant optical response at an appropriate frequency. We have carried out this investigation using both analytical approximations and a variety of approximate numerical techniques, including large-scale computer simulations. Finally, we briefly describe some work in progress, in which a composite composed of materials with a purely guardratic response can exhibit an enhanced curbic response. (AN)

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Document Details

Document Type
Technical Report
Publication Date
Oct 18, 1994
Accession Number
ADA290640

Entities

People

  • David G. Stroud

Organizations

  • Ohio State University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Composite Materials
  • Dielectrics
  • Electric Fields
  • Frequency
  • Geometry
  • Intensity
  • Materials
  • Optical Properties
  • Particles
  • Percolation
  • Physics
  • Refraction
  • Refractive Index
  • Second Harmonic Generation
  • Surface Plasmon Resonance
  • Surface Plasmons
  • Three Dimensional

Readers

  • Nanocomposite Materials Science
  • Optical Physics and Photonics.
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.