The Comparative Extinguishment Performance and Thermal Decomposition Products of Halon Alternative Agents.

Abstract

Halon 1301, Halon 1211, and eleven alternative fire-fighting agents were compared for extinguishment effectiveness and thermal decomposition product generation, using a laboratory-scale test apparatus having methane as the fuel. Chemical analysis was conducted using a magnetic sector mass spectrometer with simultaneous measurement of oxygen consumption and carbon dioxide, water, and acid gas production. Chemical mechanisms are advanced to explain how halogenated hydrocarbons extinguish fires. The major conclusion was that the alternative agents were not as effective at fighting fires as Halons and that greater amounts of acid gases were produced during extinguishment. Hydrogen fluoride was found to be the predominant thermal decomposition product for all agents. jg

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1994
Accession Number
ADA291161

Entities

People

  • Robert A. Filipczak

Organizations

  • Federal Aviation Administration

Tags

Communities of Interest

  • Biomedical
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Aircrafts
  • Calorimeters
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Decomposition
  • Detectors
  • Exothermic Reactions
  • Fire Extinguishers
  • Fire Fighting
  • Fires
  • Flow Rate
  • Heat Energy
  • Heat Of Combustion
  • Measurement
  • Test Methods
  • Thermodynamics

Readers

  • Analytical Chemistry
  • Fire Suppression Systems Design.
  • Organic Chemistry