Design of a Laboratory Study of Contaminant Film Darkening in Space.

Abstract

One of the most deleterious effects of spacecraft contaminant films is the increase in solar absorptance of optics, such as silvered fused-silica thermal control mirrors or solar cell cover slips. However, this effect cannot currently be predicted with precision. Here we discuss the design of a laboratory program to enhance the quantitative understanding of this effect, as determined by the composition of the contaminant film and subsequent simulated environmental radiation-induced darkening. This effort includes four major elements: the quantitative identification of the classes of organic materials likely to be precursors of photochemically deposited contaminant films; prediction of these materials' sensitivities to energetic irradiation in the space environment; measurement of rates of deposition and optical absorption spectra of photochemically deposited films on fused silica; and the measurements of further film darkening by irradiation with electrons, vacuum ultraviolet light, and ions. Each of these elements is discussed. A set of organic materials that have been chosen as analogs for major classes of spacecraft contaminants is presented, including the rationale for their selection and a prioritization of their potential importance. Apparatus design and performance and early experimental results are also described. jg

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1993
Accession Number
ADA291605

Entities

People

  • D. F. Hall
  • G. S. Arnold
  • H. S. Judeikis
  • Michael R. Hill
  • R. C. Young Owl

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Biomedical
  • Sensors
  • Space

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Synthesis
  • Chemistry
  • Liquid Chromatography
  • Mass Spectrometry
  • Material Degradation Processes
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Optical Materials
  • Optical Properties
  • Organic Chemistry
  • Physics Laboratories
  • Polymer Degradation
  • Spectra

Fields of Study

  • Physics

Readers

  • Environmental Engineering.
  • Spectroscopy.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene
  • Space