A Convenient Synthesis of Diaminoglyoxime and Diaminofurazan: Useful Precursors for the Synthesis of High Density Energetic Materials.

Abstract

The reaction of glyoxime (4) and hydroxylamine hydrochloride in aqueous sodium hydroxide was found to be a safe and inexpensive method for the preparation of multigram quantities of diaminoglyoxime (5). Potassium hydroxide mediated dehydration of 5 furnished diaminofurazan (1) in good yield of exceptional purity. The ready availability of 1 and 5 has facilitated the synthesis of new energetic furazan derivative MNOTO (B). jg

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Document Details

Document Type
Technical Report
Publication Date
Mar 08, 1995
Accession Number
ADA292429

Entities

People

  • Ananthakrishnan Gunasekaran
  • Joseph H. Boyer
  • Mark L. Trudell
  • Thiruvalam Jayachandran

Organizations

  • University of New Orleans

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Amines
  • Anhydrides
  • Availability
  • Chemical Synthesis
  • Chemistry
  • Cold Water
  • Energetic Materials
  • High Density
  • Hydroxides
  • Materials
  • Military Research
  • Optical Materials
  • Potassium
  • Precursors
  • Sodium Hydroxide
  • Stainless Steel
  • Water

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry