Fabrication and Evaluation of Nanoelectrode Ensembles.
Abstract
An electroless deposition procedure for filling the pores in nanoporous filtration membranes with metal (gold) nanowires is described. This method allows us to routinely prepare ensembles of gold nanodisk electrodes in which the nanodisks have diameters as small as 10 nm. Results of electrochemical experiments at ensembles of 30 nm-diameter and 10 nm-diameter gold-disk electrodes are described. The electrochemical response characteristics of these nanoelectrode ensembles are in agreement with predictions of the relevant electrochemical theories. Cyclic voltammetric detection limits for electroactive species at ensembles containing 10 nm-diameter gold disks can be as much as 3 orders of magnitude lower than at a large-diameter gold-disk electrode.
Document Details
- Document Type
- Technical Report
- Publication Date
- Apr 18, 1995
- Accession Number
- ADA293465
Entities
People
- Charles R. Martin
- Vinod P. Menon
Organizations
- Colorado State University