The Alkoxide Ligand in Olefin and Acetylene Metathesis Reactions.

Abstract

The use of alkoxides as ancillary' ligands in the organometallic chemistry and catalysis of the early transition metals is reviewed. The review includes acetylene metathesis, olefin metathesis, ring-opening metathesis polymerization, and polymerization of alkynes. In all cases, well-defined initiators are employed and the polymerization process is living. jg

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Document Details

Document Type
Technical Report
Publication Date
Jun 14, 1995
Accession Number
ADA295713

Entities

People

  • R. R. Schrock

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Acetylenes
  • Alkenes
  • Alkynes
  • Chemical Reactants
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Decomposition
  • Equations
  • Exchange Reactions
  • Explosives Initiators
  • Low Temperature
  • Metals
  • Organic Chemistry
  • Polymerization
  • Transition Metals

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology