Photo-Assisted Epitaxial Growth for III-V Semiconductors. Selective Area Epitaxy.

Abstract

We have investigated laser-enhanced growth of GaAs by metal-organic molecular beam epitaxy (MOMBE) with triethylgallium (TEGa) and solid arsenic and by chemical beam epitaxy (CBE) with TEGa and a safer, alternative organometallic precursor, tris dimethylaminoarsenic (TDMAAs), to the highly toxic arsine. We discovered that with TDMAAs we can increase the laser-enhanced growth temperature window by 100 deg C, as compared to that with arsine or arsenic. CBE growth of InP and InGaP using tris- dimethylaminophosphorus (TDMAP) and tertiarybutylphosphine (TBP) is also reported. We discovered the etching effect of TDMAAs and TDMAP, and investigated laser-enhanced etching of GaAs by TDMAAs. We also investigated laser-enhanced carbon and silicon doping in GaAs with diiodomethane (CI2H2) and disilane, respectively. We can achieve a two-order-of-magnitude enhancement in p-type carbon doping with CI2H2 by laser irradiation. Finally, we report on lateral bandgap variation by laser-modified compositional change in InGaAs/GaAs multiple quantum wells grown by MOMBE and CBE. jg p.3

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Document Details

Document Type
Technical Report
Publication Date
Mar 03, 1995
Accession Number
ADA298197

Entities

People

  • C. W. Tu
  • H. K. Dong

Organizations

  • University of California, San Diego

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical
  • Energy and Power Technologies
  • Space

DTIC Thesaurus Topics

  • Chemical Reactions
  • Chemical Vapor Deposition
  • Chemistry
  • Compound Semiconductors
  • Critical Temperature
  • Crystal Growth
  • Electronics Industry
  • Electronics Laboratories
  • Epitaxial Growth
  • Heterojunction Bipolar Transistors
  • Heterojunctions
  • Mass Spectrometry
  • Measurement
  • Optics
  • Pressure Measurement
  • Quantum Wells
  • Semiconductors

Fields of Study

  • Materials science

Readers

  • Analytical Chemistry
  • Semiconductor Device Technology

Technology Areas

  • Directed Energy
  • Microelectronics
  • Microelectronics - Graphene
  • Quantum Computing