Deactivation of Vibrationally-Excited NO and CO2 by O-Atoms.

Abstract

Spectral measurements of the limb radiation of the earth have shown that emissions from the NO(v=1) and CO2(0l (1)0) states dominate the nighttime radiance seen at long wavelengths. At the high altitudes of the thermosphere, the deactivation of the aforementioned molecules helps regulate the temperature. A knowledge of the kinetics of deactivation of these molecules is therefore needed to accurately model the temperature of the thermosphere. Sharma and coworkers have developed a procedure to invert the profiles of the limb emissions to determine the vertical distributions of local atmospheric properties. This procedure can be used to monitor local NO, NO(v=1), CO2 and O densities as well as translational temperatures. They have shown the inversion procedure is sensitive to the rate of the reaction for deactivation of NO(v=1) and CO2(01(1)0) by O atoms. jg p.6

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1994
Accession Number
ADA298581

Entities

People

  • H. V. Lilenfeld

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Carbon Monoxide Lasers
  • Detection
  • Detectors
  • Electric Discharges
  • Emission
  • Equations
  • Flow Rate
  • Ground State
  • High Temperature
  • Laser Beams
  • Laser Diodes
  • Lasers
  • Measurement
  • Microwaves
  • Nitrogen Oxides
  • Partial Pressure
  • Radiation

Readers

  • Computational Modeling and Simulation
  • Molecular Photonics/Laser Physics
  • Space/Atmospheric Physics.