Dichloroborane-Dimethyl Sulfide, A Highly Selective Reducing Agent for Reduction of Organyl Azides to Amines.

Abstract

Dichloroborane-dimethyl sulfide reduces a variety of organyl azides, including primary, secondary, tertiary alkyl, cycloalkyl, aromatic and benzylic, to the corresponding amines in excellent yields. The reagent is highly selective and many functional groups, such as halogen, ester, nitrile, aliphatic and aromatic nitro, survive in this process. jg p.3

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Document Details

Document Type
Technical Report
Publication Date
Sep 19, 1995
Accession Number
ADA299130

Entities

People

  • Ashok M. Salunkhe
  • Herbert C. Brown

Organizations

  • Purdue University

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Amines
  • Chemical Synthesis
  • Chemistry
  • Civil Engineering
  • Ethers
  • Magnesium Compounds
  • Military Research
  • New York
  • Nitriles
  • Nitro Compounds
  • Nitrogen
  • Organic Chemistry
  • Organic Compounds
  • Procurement
  • Reducing Agents
  • Surface Warfare
  • United States

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry