Evaluation of High Temperature Structural Adhesives for Extended Service - Phase V.

Abstract

This report documents the work performed by the Boeing Aerospace Company for the National Aeronautics and Space Administration, Langley Research Center, under contract NAS1-15605, Phase V. The primary objective of this program was to evaluate three experimental polymers as high temperature structural adhesives for bonding 6Al- 4V titanium and 17-7 PR stainless steel for long-term applications at 505K (450 F). The three experimental polymers were polyphenylquinoxaline (PPQ), polyimide (STPI/LaRC-2), and polyarylene ether (PAE SO2). A fourth polymer, LaRC-TPI, was evaluated as an adhesive for titanium honeycomb sandwich bonding. Surface preparations for the metal adherends were 10 volt chromic acid anodize and Pasa-Jell 107 for titanium, and 2 volt sulfuric acid anodize for the stainless steel. The test matrix for evaluating the experimental adhesives consisted of metal-to-metal titanium lap shear, crack extension, and climbing drum peel specimens tested initially at temperatures ranging from 219K (-65 F) to 505K (450 F). Durability was determined as a function of strength retention after exposure to a variety of aerospace vehicle environments. These included humidity exposure (332K (120 F)/95% R.H.) for 1,000 hours, high temperature exposure (450K (350 F) and 505K (450 F)) for up to 3,000 hours, and stressed exposure to hydraulic fluid (Skydrol). Durability of bonded stainless steel joints was determined on an abbreviated test matrix. PPQ and STPl/LaRC-2 polymers maintained structural durability in all test environments.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1987
Accession Number
ADA300885

Entities

People

  • C. L. Hendricks
  • J. N. Hale
  • S. G. Hill
  • W. G. Dumars

Organizations

  • Boeing

Tags

Communities of Interest

  • Human Systems
  • Space

DTIC Thesaurus Topics

  • Adhesives
  • Cell Size
  • Chromic Acid
  • Environmental Exposure
  • Failure Mode And Effect Analysis
  • Glass Transition Temperature
  • High Temperature
  • Honeycomb Cores
  • Materials
  • Mechanical Working
  • Peel Strength
  • Resistance
  • Shear Strength
  • Stainless Steel
  • Structural Integrity
  • Tensile Properties
  • Tensile Strength

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Polymer Science and Engineering.
  • Surface Coatings Technology.

Technology Areas

  • Space