Synthesis and Structural Characterization of Alkyl, Gallium-Phosphorus Compounds, X-Ray Crystal Structures of (Me3CCH2)2(Cl)Ga.P(SiMe3)3, R2GaP(SiMe3)2GaR2Cl(R=Me3CCH2 and Me3SiCH2), and ((R)(X)GaP(SiMe3)2)2 (R=Me3CCH2, X=Cl; R=Me3CCH2, X=Me3CCH2; R=Me3SiCH2,X=Br).

Abstract

Continued activity in the development of single-source precursors to 13-15 semiconductor materials has motivated our laboratory to investigate the synthesis of novel organogallium phosphorus compounds which might serve as potential precursors to GaP. Recently, our efforts to produce the gallium-phosphorus bond have led to the formation of interesting ring compounds and simple adducts.

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Document Details

Document Type
Technical Report
Publication Date
Dec 20, 1995
Accession Number
ADA302851

Entities

People

  • Arnold L. Rheingold
  • Peter S. White
  • Richard L. Wells
  • Ryan A. Balwin
  • William T. Pennington

Organizations

  • Duke University

Tags

Communities of Interest

  • Advanced Electronics
  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Crystals
  • Diffraction
  • Diffractometers
  • Dihedral Angle
  • Mass Spectrometry
  • Materials
  • Military Research
  • Phosphorus
  • Phosphorus Compounds
  • Radiation
  • Scattering
  • Spectra
  • Universities
  • X Rays

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Systems Analysis and Design

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene