New Mechanism for the Desorption of Excited Atoms by Photon Bombardment of Alkali Halide Crystals.

Abstract

We report measurements of photon-stimulated desorption of excited atoms from LiF and NaCl crystal surfaces. Based on these measurements, we propose a new model of photon-initiated, defect-mediated desorption involving exoergic surface reactions between alkali dimers and halogens. This model consists of two steps: (a) reactants are formed at the surface, directly or by the migration to the surface of holes and defects created in the near surface bulk, due to uv photon bombardment, and (b) excited alkali atoms are emitted following a reaction between the alkali and halogen surface species. jg p2

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Document Details

Document Type
Technical Report
Publication Date
Apr 04, 1991
Accession Number
ADA302907

Entities

People

  • A. V. Barnes
  • C. S. Ewig
  • Dong Liu
  • P. H. Bunton
  • R. G. Albridge

Organizations

  • Vanderbilt University

Tags

Communities of Interest

  • Biomedical
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Atoms
  • Chlorine
  • Contracts
  • Crystals
  • Desorption
  • Electrons
  • Energy
  • Energy Transfer
  • Excitation
  • Free Electrons
  • Ground State
  • Halogens
  • Measurement
  • Photon Bombardment
  • Radiation
  • Surface Reactions
  • Synchrotron Radiation

Fields of Study

  • Physics

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Molecular Photonics/Laser Physics