Investigation of Oceanic Organic Chemistry Using State-of-the-Art Laser Based Analytical Techniques.

Abstract

The fluorescence of global seawater has been investigated using a sensitive laser-induced fluorometry system. In surface seawater, fluorescence is low due to photochemical bleaching. Fluorescence intensity increases with increasing depth in the oceans to about 500 to 1000 m; below this depth, seawater fluorescence is generally constant. Sediment porewaters are much more fluorescent than the overlaying seawater. Both porewater fluorescence, and the dissolved organic carbon (DOC) concentration, increase with depth in the sediment. Fluorescence of porewaters can thus be used to provide an estimate of the DOC content. Because of the higher fluorescence in porewaters in comparison of seawater, fluorescence provides a means of estimating the amount of DOC diffusing out of sediments into seawater. The fluorescence measurements indicate that this source of DOC is only a minor contributor to the oceanic DOC budget. (AN)

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1996
Accession Number
ADA303611

Entities

People

  • Jeffrey Bada

Organizations

  • Scripps Institution of Oceanography

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Arctic Ocean
  • Aromatic Hydrocarbons
  • Chemical Synthesis
  • Chemistry
  • Cyclic Hydrocarbons
  • Deep Water
  • Detectors
  • Fluorescence
  • Laser Induced Fluorescence
  • Lasers
  • Liquid Chromatography
  • Measurement
  • Military Research
  • Optical Materials
  • Organic Chemistry
  • Organic Compounds
  • Sediments

Fields of Study

  • Environmental science

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Materials Science and Engineering.
  • Research Science/Academic Research

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers